There is an alternate method for taking spectra (the "dispersive" or "scanning monochromator" method), where one wavelength at a time passes through the sample. The dispersive method is more common in UV-Vis spectroscopy, but is less practical in the infrared than the FTIR method. One reason that FTIR is favored is called "Fellgett's advantage" or the "multiplex advantage": The information at all frequencies is collected simultaneously, improving both speed and signal-to-noise ratio. Another is called "Jacquinot's Throughput Advantage": A dispersive measurement requires detecting much lower light levels than an FTIR measurement.[3] There are other advantages, as well as some disadvantages,[3] but virtually all modern infrared spectrometers are FTIR instruments.
Sunday, October 30, 2011
FTIR
Fourier transform infrared (FTIR) spectroscopy is a measurement technique that allows one to record infrared spectra. Infrared light is guided through an interferometer and then through the sample (or vice versa). A moving mirror inside the apparatus alters the distribution of infrared light that passes through the interferometer. The signal directly recorded, called an "interferogram", represents light output as a function of mirror position. A data-processing technique called Fourier transform turns this raw data into the desired result (the sample's spectrum): Light output as a function of infrared wavelength (or equivalently, wavenumber). As described above, the sample's spectrum is always compared to a reference.
There is an alternate method for taking spectra (the "dispersive" or "scanning monochromator" method), where one wavelength at a time passes through the sample. The dispersive method is more common in UV-Vis spectroscopy, but is less practical in the infrared than the FTIR method. One reason that FTIR is favored is called "Fellgett's advantage" or the "multiplex advantage": The information at all frequencies is collected simultaneously, improving both speed and signal-to-noise ratio. Another is called "Jacquinot's Throughput Advantage": A dispersive measurement requires detecting much lower light levels than an FTIR measurement.[3] There are other advantages, as well as some disadvantages,[3] but virtually all modern infrared spectrometers are FTIR instruments.
There is an alternate method for taking spectra (the "dispersive" or "scanning monochromator" method), where one wavelength at a time passes through the sample. The dispersive method is more common in UV-Vis spectroscopy, but is less practical in the infrared than the FTIR method. One reason that FTIR is favored is called "Fellgett's advantage" or the "multiplex advantage": The information at all frequencies is collected simultaneously, improving both speed and signal-to-noise ratio. Another is called "Jacquinot's Throughput Advantage": A dispersive measurement requires detecting much lower light levels than an FTIR measurement.[3] There are other advantages, as well as some disadvantages,[3] but virtually all modern infrared spectrometers are FTIR instruments.
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