This page explains how to use an infra-red spectrum to identify the presence of a few simple bonds in organic compounds.
The infra-red spectrum for a simple carboxylic acid
Ethanoic acid
Ethanoic acid has the structure:
You will see that it contains the following bonds:
carbon-oxygen double, C=O
carbon-oxygen single, C-O
oxygen-hydrogen, O-H
carbon-hydrogen, C-H
carbon-carbon single, C-CThe carbon-carbon bond has absorptions which occur over a wide range of wavenumbers in the fingerprint...
Friday, November 4, 2011
Instrumental Techniques for Analytical Chemistry
Introduction
Infrared (IR) spectroscopy is one of the most common spectroscopic techniques used by organic and
inorganic chemists. Simply, it is the absorption measurement of different IR frequencies by a sample
positioned in the path of an IR beam. The main goal of IR spectroscopic analysis is to determine the
chemical functional groups in the sample. Different functional groups absorb characteristic frequencies
of IR radiation. Using various sampling accessories, IR spectrometers can accept a wide range of sample
types such as gases, liquids, and solids. Thus, IR spectroscopy is an important and popular tool for
structural elucidation and compound identification.
IR Frequency Range and Spectrum...
Infrared Spectroscopy Chemical Analisys
General Uses
• Identification of all types of organic and many types of inorganic compounds
• Determination of functional groups in organic materials
• Determination of the molecular composition of surfaces
• Identification of chromatographic effluents
• Quantitative determination of compounds in mixtures
• Nondestructive method
• Determination of molecular conformation (structural isomers) and stereochemistry (geometrical
isomers)
• Determination of molecular orientation (polymers and solutions)
Common Applications
• Identification of compounds by matching spectrum of unknown compound with reference
spectrum (fingerprinting)
• Identification of functional groups in unknown substances
Identification...
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